I can't see his saying,
"Can't work 'em!" in the script.
I try to make the full sentence for it because I'm gonna check out the thing for me to understand.
"He(
= Chandler) can't work them(=
his plan for messing with Phobe")
--------The script goes: ----------------[Cut to the hallway where Phoebe is conferring with Rachel.]
Phoebe: He's not backing down. He went to get lotion.
Joey: (entering the hall) Oh man! Aren't you guys done yet?! I wanna sit in my chair!
Rachel: Joey look, just look at it this way, the sooner Phoebe breaks Chandler the sooner this is all over and out in the open.
Joey: Ooh!
Rachel: Okay!
Joey: I like that! (To Phoebe) Oh, okay! Show him your bra! He's afraid of bras!
Can't work 'em! (He swiftly rips open the front of Phoebe's dress revealing her bra.)
Phoebe: Joey! (Examining the dress.) Wow, you didn’t rip off any buttons.
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I write down The site for full scripts of this episode for you to see my question well.
http://ufwebsite.tripod.com/scripts/514efo.htm