Hi, We normally speak of 'laws' or 'regulations' of a country, not 'rules. Both can be used. payment with a PayPal account - suggests the account is used as the method of payment payment from a PayPal account - suggests the account is the source of the payment, ie where it comes from.
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RazerSentence: Do the rules of my country allow international payment with/from PayPal account?I would choose from.