All three may have the same meaning of "during," but "while" and "as" have other usages as conjunctions, so you have to take care not to introduce any ambiguity. "While" can mean "whereas," introducing a contrast: He was driving a golf cart, while I was driving a car. "As" can mean "because": As I was driving a car, I couldn't have possibly have leaned down to tie my shoes.
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"As" can mean "because":He was driving a golf cart, while I was driving a car.
As I was driving a car, I couldn't have possibly h