Hi Robsee, When I opened the window, the cat jumped out. As a generalization, we don't use past perfect when the meaning is clear without it. It seems very clear to me in this example that the window was opened first, because cats don't like to jump through glass!
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PinenutWhen I opened the windows.... This describes the exact moment in time.Interesting. I hear the sentence the same way.
the cat jumped out at the same moment. The two events took place at the same time. That is why you don't use different tenses.