As a non native speaker, it is difficult for me to understand phonetics. So please give me the list of words
1. which need 'an' but not start with vowels
2. which need 'a' but start with vowels
There is no such list. Instead, you need to learn the rule: it is NOT the letter that the word begins with, but the SOUND.
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There is no such list. Instead, you need to learn the rule: it is NOT the letter that the word begins with, but the SOUND.