" is adverbial, modifying "sing". "that was rising away" modifies "voice". The object of "thought" is "(that) it was like a voice up in the air".
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park sang joonThen I was wondering what role the comma plays before "that."To a modern reader (or to me, at least), it makes the clause feel non-defining rather than defining. However, I couldn't say for sure that the author put the comma there for that reason. It may be an older punctuation style, or it may simply be the author's whim.