Is subconsciously correctly used? No. It means 'without thinking, without awareness', so it does not fit your example. . ,Is this word order correct ' most about first'? It's not wrong. But I don't understand what you mean by 'or anything else'. I don't want to start guessing. You need to try to say it another way.
Would you care to tell me please whether I could replace the word subconsciously? If I get rid of 'anything else' would that make the sentence better? Thank you
Would you care to tell me please whether I could replace the word subconsciously? You could say 'instinctively'. But really, I have trouble understanding your thought. Do you mean that they do not do it intentionally?
How about just saying 'People name the people they care most about f