No logic; simple usage. Different verbs require different prepositions, or none at all: Explain to me Say to me Tell me Ask me Shout at me Elucidate for me etc.
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Nona The Brit 'explain me' means that I myself am the subject of the explanation.That's an important point. 'explain me' should be avoided for that reason alone, if not specifically meant "I myself."
I was trying to puzzle out a rule for this