Because "all of" is just used before plural nouns, and "sugar" is a non-countable noun, so singular. all of + plural all + plural all + singular
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macriswhy can I say "all of my friends like watching tv" (as well as "all my friends like watching tv), but I can't say "all of sugar is sweet" ( and I have to say " all sugar is sweet")?You are comparing the wrong things.