It means that if his helper goes to Washington, Mr. Khoshtip won't need to.
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khoshtipMr. Khoshtip has to go to Washington on a business trip unless his associate volunteers to go.You need the 'to' between 'volunteers' and 'go'.
khoshtipunless his associate volunteers to go.More clearly:
khoshtipunless his associate volunteersWith volunteers as a noun this is OK without 'to'. However, the expression associate volunteer is not likely to refer to any real entity. There is no such thing as a principal volunteer, an assistant volunteer, or an associate volunteer. That's why Philip and I are steering you away frtogo.
CalifJimNote that "volunteers" is a verb, not a noun.It was the key. Thanks.