Nnit He asked each of the students to speak English. You are referring to a specific group of students while pointing to each and every one of them. Nnit There were a lot of people at the concert.
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NnitHe asked each of the students to speak English.You are referring to a specific group of students while pointing to each and every one of them.
NnitThere were a lot of people at the concert.You are referring to a non-specific large group of people (all of them) without focusing on who they were.
NnitDoes the word 'of' always need a determiner following it???No. Not at all. The use of a determiner (or not) depends on the following noun phrase, not on the word 'of'.