Doesn't sound very correct to me. What are you trying to say? Two verbs, but when?
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wojtek kaAlthough she had been a student, she already started her professional careerI would just exchange the tenses.
wojtek kaDoes your sentence mean that she started her career before she was a student?No.
wojtek kaWhat I want to say is: she was a student and she supposed to start her professional work after finishing her studies. She was smart enough to start her academic career when she was still a student.Right. That's what I though