He is sweet [sweet is not modifying a noun]
Although in the second case sweet is an adjective:
He is a sweet person
[Here sweet is modifying person so it's an adjective]
He is sweet [sweet is not modifying a noun] It's an adjective that describes the pronoun 'he'.
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He is sweet [sweet is not modifying a noun]
It's an adjective that describes the pronoun 'he'.