The verb "be" is used alone as an ordinary (main) verb. It is also used as an auxiliary verb. The word "be" is a bare infinitive. When "be" is a main verb, it has various different forms. For example: am, are, is, was, were
could and be are two different words, each with their own use. Your question is similar to asking what the difference is between did and did go or between may and may find. could is always followed by another verb: could go, could find, could see, could decide, could sleep, could eat, could rest, could work, and could be.