"When he found nothing was available, he not only ordered it but also kindly completed the form to request the item be reserved for me" He obviously ordered the item. We presume that since it is a store, other items were on order. In language proficiency tests like TOEIC, students are expected to exercise common sense and demonstrate an overall understanding of the sort of situation presented rather than simply focus in on a row of vocabulary items in a sentence.
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Niue the TOEIC book says ONLY A (= Delivering the item to a customer.) is correct.I agree with the book, as I hope I explained clearly enough.
Niue (The book says the correct answer is D, "Ordering an additional item.")The quote I indicated above says that he did.